Transparent flexible energy storage devices are considered as important chains in the next‐generation, which are able to store and supply energy for electronic devices. Here, aluminum‐doped zinc oxide (AZO) nanorods (NRs) and nickel oxide (NiO)‐coated AZO NRs on muscovites are fabricated by a radio frequency (RF) magnetron sputtering deposition method. Interestingly, AZO NRs and AZO/NiO NRs are excellent electrodes for energy storage application with high optical transparency, high conductivity, large surface area, stability under compressive and tensile strain down to a bending radius of 5 mm with 1000 bending cycles. The obtained symmetric solid‐state supercapacitors based on these electrodes exhibit good performance with a large areal specific capacitance of 3.4 mF cm−2, long cycle life 1000 times, robust mechanical properties, and high chemical stability. Furthermore, an AZO/NiO//Zn battery based on these electrodes is demonstrated, yielding a discharge capacity of 195 mAh g−1 at a current rate of 8 A g−1 and a discharge capacity of over 1000 cycles with coulombic efficiency to 92%. These results deliver a concept of opening a new opportunity for future applications in transparent flexible energy storage.
https://doi.org/10.1002/smll.202000020
